Electrochemical Behavior and Voltammetric Determination of a Manganese(II) Complex at a Carbon Paste Electrode
نویسندگان
چکیده
Investigation of the electrochemical behavior using cyclic voltammetry and detection of [Mn(2+)(thiophenyl-2-carboxylic acid)2 (triethanolamine)] with adsorptive stripping differential pulse voltammetry. The electrochemical behavior of a manganese(II) complex [Mn(2+)(thiophenyl-2-carboxylic acid)2(triethanolamine)] (A) was investigated using cyclic and differential pulse voltammetry in an acetate buffer of pH 4.6 at a carbon paste electrode. Further, an oxidation-reduction mechanism was proposed. Meanwhile, an adsorptive stripping differential pulse voltammetric method was developed for the determination of manganese(II) complex.
منابع مشابه
Voltammetric determination of cysteine at a carbon paste electrode modified with Cu(II)-salen complex
The electrochemical behavior of a modified carbon paste electrode (MCPE) with N,N′ethylenbis(salicylideneiminato)copper(II) complex ([Cu(II)-Salen]) was investigated as a newsensor for cystein. The Britton-Robinson buffer with pH 5, 10% modifier in electrode, potentialscanning rate of 20 mVs-1 and puls height of 50 mV were used as the optimum condition for thedetermination of cysteine using car...
متن کاملVoltammetric Determination of Tryptophan Using a Carbon Paste Electrode Modified with Magnesium Core Shell Nanocomposite and Ionic Liquids
A novel carbon paste electrode modified with ionic liquid (n-hexyl-3-methylimidazolium hexafluoro phosphate) and magnetic core-shell manganese ferrite nanoparticles (MCSILCPE) was fabricated. The electrochemical study of the modified electrode, as well as its efficiency for electro-oxidation of tryptophan, is described. Cyclic voltammetry (CV), choronoamperometry (CHA) and square wave voltammet...
متن کاملSilica Nanoparticles Modified Carbon Paste Electrode as a Voltammetric Sensor for Determination of Diclofenac
The present study describes the use of a new carbon paste electrode modified by means of Silica nanoparticles prepared by a simple and rapid procedure for the determination of sodium diclofenac (DCF). Moreover, the present study focuses on the characterization of electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) of the prepared Silica NPs-CPE. In this work, The...
متن کاملSimultaneous Voltammetric Determination of Ascorbic Acid and Uric Acid Using a Modified Multiwalled Carbon Nanotube Paste Electrode
This paper describes the development, electrochemical characterization and utilization of novel modified molybdenum (VI) complex-carbon nanotube paste electrode for the electrocatalytic determination of ascorbic acid (AA). The electrochemical profile of the proposed modified electrode was analyzed by cyclic voltammetry (CV) that showed a shift of the oxidation peak potential of AA about 235 mV ...
متن کاملVoltammetric and Potentiometric Behavior of 2-Pyridinethiol, 2-Mercaptoethanol and Sulfide at Iron(II) Phtalocyanine Modified Carbon-Paste Electrode
A carbon-past electrode modified with iron(II) phathalocyanine (FePc) was used as a sensitive potentiometric sensor for determination of 2-pyridinethiol (2PT). 2-mercaptoethanol (2ME) and sulfide ion in aqueous solutions. The modified electrode acts as an electrocatalyst for oxidation of these compounds, and lowers the overpotential for oxidation reactions by more than 400 mV, compared to t...
متن کامل